Oxidative esterification of aldehydes using cytosine palladium complex immobilized on SBA-15

کد مقاله : 1173-ICOC

نویسندگان

نسترن بغدادی * دانشجو

چکیده مقاله

Esters are one of the most important fundamental and significant functional group in organic chemistry and chemical industry because they are used in high value products such as cosmetics, biofuel, pharmaceuticals, surfactant, and food ingredient. In this study, an efficient, economic, sustainable, and green protocol for oxidative esterification reaction has been developed. A one-pot direct transformation of aliphatic, aromatic, and unsaturated aldehydes into esters in the presence of hydrogen peroxid has been carried out over mesoporoues SBA-15 supported palladium nanocatalyst (Pd-Cyt-SBA-15) under reflux condition. Pd-Cyt-SBA-15 nanocatalyst demonstrated excellent reusability and stability and could be recycled up ttimes whit-out loss of significant reactivity The present work benefits of mild reaction conditions, high efficientcy, simple product isolation and shorter reaction times.

کلیدواژه ها

Oxidative Esterification, Aldehydes, Cytosine Palladium Complex , SBA-15

وضعیت: پذیرفته شده