| Synthesis of 21-thiaporphyrins using oxidized graphitic carbon nitride functionalized with aminosulfonic acid |
| کد مقاله : 1178-ICOC |
| نویسندگان |
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زهرا آخوندی *1، رامین قربانی واقعی2، آذین خوارزمی3 1دانشگاه بوعلی سینا 2دانشگاه گیلان 3دانشگاه بوعلی |
| چکیده مقاله |
| In this study, a metal-free solid acid catalyst based on oxidized graphitic carbon nitride was designed and synthesized, which exhibited excellent performance in the green synthesis of new 21- thiaporphyrin derivatives. Owing to its completely non-metallic structure, this catalyst offers higher safety, lower cost, and greater environmental compatibility compared to metal-based catalysts. The presence of this catalyst resulted in increased yield, reduced reaction time, improved selectivity, and allowed the process to proceed under milder conditions. Moreover, the avoidance of hazardous organic solvents and high temperatures makes this method more efficient and safer from a greenchemistry perspective. In addition to its high thermal stability, the catalyst features easy separation and reusability without significant loss of activity—characteristics that highlight its economic and environmental importance |
| کلیدواژه ها |
| oxidized graphitic carbon nitride, O-g-C3N4/Am-SO3H, 21-thiaporphyrin, One-pot reaction |
| وضعیت: پذیرفته شده |