| Electrocatalytic performance of metal porphyrin species anchored on porous nanocomposite substrates and their effect on the oxidation-reduction pathways of organic precursors |
| کد مقاله : 1294-ICOC |
| نویسندگان |
|
مریم احمری نیت *1، رعنا رودکی2، وحید خاکی زاده2، فاطمه نجابت3 1دانشجو ام وابستگی سازمانی ندارم 2فلکه چهارم تهرانپارس خیابان وفادار شرقی دوراهی رهبر دانشکده هوافضا خوابگاه طلاکوب 3استاد دانشگاه امیر کبیر |
| چکیده مقاله |
| Abstract Electrochemistry is the science that studies chemical-electrical processes and the conversion of energy in oxidation-reduction reactions, where a chemical reaction is driven by the application of electrical energy (such as electrolysis). It provides a green method for organic synthesis that produces less waste and has higher selectivity compared to conventional chemical methods [1]. The advantages of electrochemistry include the ability to perform reactions under mild conditions and high selectivity, which is due to the possibility of precise control of the electrode potential and precise targeting of the oxidation/reduction process [2]. The aim of this research is to construct a heterogeneous chemically modified electrode (CME) obtained by immobilizing an metal porphyrin complex on a porous, highly conductive substrate. This electrocatalytic system acts as an indirect redox mediator for the electrochemical oxidation of some organic compounds. The performance of this composite electrode is such that it causes a decrease in the oxidation potential of most organic compounds and improves the electron transfer kinetics compared to unmodified electrodes, thus providing an energetically green route for this reaction in the synthesis of chemicals. [3] |
| کلیدواژه ها |
| Keywords: Electrosynthesis, Electrochemistry,Metaloporphyrin,Modified Electrode, Benzyl Alcohol Oxidation |
| وضعیت: پذیرفته شده |