| Application of functionalized Fe-based metal-organic frameworks (Fe-MOFs) with CuO in the preparation of triazoles |
| کد مقاله : 1319-ICOC |
| نویسندگان |
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ماهرخ فرخ1، میلاد محمدی رسول2، محمدعلی زلفی گل *2، مریم حجامی2 1دانشگاه بوعلی سینا همدان 2همدان چهارباغ احمدی روشن دانشگاه بوعلی سینا دانشکده شیمی |
| چکیده مقاله |
| The development of porous materials with their unique properties has become a very attractive necessity. Metal-organic frameworks (MOFs) are considered the most important class of porous materials, with numerous regular pores observed in their structure. This class of porous compounds is designable due to choosing suitable ligands and metals. The high designability, good thermal and chemical stability, and abundant porosity of MOFs have created wide applications for this class of crystalline materials. In recent years, metal-organic frameworks (MOFs) have been developed and are widely used in optics, sensors, gas adsorption and separation, gas storage, catalysis, and drug delivery [1-2]. Click reactions are among the most important chemical reactions that are very important in preparing organic compounds for various purposes. Triazole rings formed by click chemistry confer pharmacological properties to the desired compounds, converting them into biologically active compounds. Structures containing triazole rings often exhibit antibacterial, antifungal, anti-inflammatory, antiviral, antitumor, and therapeutic properties that inhibit various pathogens [3]. In this study, Fe-MOfs@CuO was prepared by loading CuO on the surface of the initial MOFs. Then, the abovementioned catalyst was used to prepare triazole compounds at ambient temperature. High product yield, synthesis under mild conditions, and the ability to recycle and reuse the catalyst are among the most important features of the current research work. |
| کلیدواژه ها |
| Keywords: Click reactions, Fe-MOFs@CuO, Metal-organic framework, Triazole, |
| وضعیت: پذیرفته شده |