| Design and synthesis nanostructured ZIF-67@CuO as an efficient photocatalyst for Azide-Alkyne Cycloaddition Reactions |
| کد مقاله : 1320-ICOC |
| نویسندگان |
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سیدمحمد گوهری پرور1، میلاد محمدی رسول2، محمدعلی زلفی گل *2 1دانشگاه بوعلی سینا 2استان همدان دانشگاه بوعلی سینا . دانشکده علوم و نفت .گروه تحقیقاتی دکتر زلفی گل |
| چکیده مقاله |
| In recent years, the development of chemical processes with green principles are very important for researchers. In this regard, the design of desired catalysts and photocatalysts has provided a new and absorbing insight [1]. In this context, zeolitic imidazolate framework (ZIFs) are an important class of porous catalysts. The ability to modify the structure of this class of compounds increases their light absorption, active sites, efficient electron transfer, and prevents electron recombination. These attractive properties of ZIFs have very good catalytic and photocatalytic properties [2]. The post-synthetic modification approach is very effective in achieving efficient catalysts and photocatalysts with the principles of green chemistry. In this context, the modification of ZIFs with nanoparticles is applicable for achieving efficient photocatalysts. ZIFs modified with nanoparticles are widely used in performing photocatalytic reactions such as oxidation/reduction reactions, degradation of environmental pollutants, click reactions, etc. [3]. On the other hand, photo click reactions are an important class of chemical reactions that are widely used in the preparation of heterocyclic compounds with biological activities. In this report, ZIF-67@CuO was used as an efficient photocatalyst to carry out the azide-alkyne cycloaddition reactions under visible light irradiation. The most important features of the above reaction include high reaction efficiency, green synthesis, and the ability to recycle and reuse the catalyst |
| کلیدواژه ها |
| Azide-Alkyne Cycloaddition, Click reaction, Photocatalyst, Visible light, ZIF-67@CuO. |
| وضعیت: پذیرفته شده |